TUT DIGITAL OPEN REPOSITORY

Recent Submissions

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    Heat-treatment (Annealing) effect on the mechanical and electrochemical performance of a synthesized AlCrFeMnNiV equi-atomic high entropy alloy (HEA) via Arc-melting and casting Technologies.
    (Sociedade Portuguesa de Electroquímica, 2021-10-25) Kanyane, L. R.; Malatji, N.; Popoola, A. P. I.
    In this work, an equi-atomic AlCrFeMnNiV HEA was synthesized by means of arc-melting and casting processes. The casted alloy ingots were heat-treated (annealed) at temperatures of 400, 600 and 800 ºC, for 2 h. The effect of the heat-treatment temperature on the HEA microstructural evolution, compressive strength and corrosion behavior was investigated. Heat-treatment temperatures of 400 and 600 ºC resulted in increased micro-hardness properties that, at 800 ºC, were drastically reduced, although a good combination between strength and ductility was observed. HEA showed an extreme decrease in the current density (J (A/cm2)), after the heat-treatment, with a lower potential (V). The heat-treated HEA demonstrated a good corrosion rate in acidic conditions, as compared to that of nickel (Ni) based, titanium (Ti) alloys and stainless steel (SS) super alloys.
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    Synthesis of equi-atomic Ti-Al-Mo-Si-Ni high entropy alloy via spark plasma sintering technique: Evolution of microstructure, wear, corrosion and oxidation behaviour.
    (Elsevier, 2019-06-19) Kanyane, L.R.; Malatji, N.; Popoola, A.P.I.; Fayomi, O.S.I.
    Equi-atomic Ti-Al-Mo-Si-Ni high entropy alloys (HEAs) with outstanding wear and oxidation properties is fabricated by means of Spark plasma sintering (SPS) technology. The influence of sintering temperature on surface microstructure, phase evolution, densification, microhardness, corrosion, wear and oxidation properties of developed Ti-Al-Mo-Si-Ni HEAs was investigated at 800 °C, 900 °C and 1000 °C. The microstructural evolutions of the synthesized HEAs were evaluated by means of scanning electron microscope coupled with energy dispersive spectroscopy (SEM/EDS). The SEM images showed no significant major porosity; however for the HEA sintered at 800 °C, the densification results prove that 2.6% porosity is present in the HEAs. XRD showed the presence of BCC and FCC solid solution structures with intermetallic precipitates of TiSi2 and Ni2Si2. The Vickers micro hardness and wear resistant properties was evaluated using diamond base micro hardness tester (EMCO) and tribometer (Rtec) respectively, with the sample sintered at 1000 °C showing maximum densification of 98.8% with microhardness of 612HV and coefficient of friction (CoF) of 0.23µ. The developed HEAs also showed good oxidation resistant behaviour after a test using thermal gravimetric analyzer (TGA).
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    Development of spark plasma sintered TiAlSiMoW multicomponent alloy: Microstructural evolution, corrosion and oxidation resistance.
    (Elsevier, 2019-01-31) Kanyane, Rudolf L.; Popoola, Patricia A.; Malatji, Nicholus
    TiAlMoSiW high entropy alloy was fabricated using spark plasma sintering under different sintering temperatures. The microstructural and morphological characteristics of the alloy were investigated using X-ray diffractometry (XRD) and scanning electron microscope (SEM) equipped with energy dispersive spectroscopy (EDS). The mechanical and corrosion properties of the alloy were tested using diamond base indentor and potentiodynamic polarization. Thermogravimetric analysis and density measurements were used to check the thermal stability and densification of the samples. Microstructural analysis of the samples showed that the samples exhibited a bcc matrix with secondary phase precipitate of TiSi2. The microhardness was found to be subject to sintering temperature and densification with high microhardness values obtained 1000 °C and 98% densification. The presence of elements that form stable protective film were attributed to the high corrosion performance of the samples. These elements also form stable oxide scales in elevated temperatures improving the thermal stability of the alloy. Excessive oxidation was noticed to occur at temperatures above 535 °C showing that the alloy has superior thermal stability than Ti-6V-4Al.
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    An Integrated value-addition in supply chain network for metal-based additive manufacturing.
    (Elsevier, 2023-01-01) Nzengue, Alliance Gracia Bibili; Mpofu, Khumbulani; Mathe, Ntombizodwa; Muvunzi, Rumbidzai; Oyesola, Moses
    The increasing speed of product development and the ability to deliver complex, near-net-shaped engineering metal parts are key benefits of additive manufacturing (AM). Producing or replacing parts by leveraging AM relies heavily on supply chain (SC) functions. Inadequately managed SC could lead to lower productivity and process waste. Hence, the aim is to integrate value-adding activities into the SC network using the principles of lean manufacturing, such as Value Stream Mapping (VSM) and flowchart. A case study of a braking system manufacturer company in South Africa was used to exploit VSM and the flowchart for reducing process waste. The result of the case study revealed that the frequent use of expedited shipping increased transportation costs and lead times required excess raw material inventory, and lengthy supplier order processing. The approach demonstrated the need to adjust the business model by virtually synchronising the flow of information across the SC players in the configuration of the entire AM production and distribution activities. The study provides a framework that can guide AM organisations in improving efficiency and achieving significant cost and time savings.
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    Investigation into process parameter optimization of selective laser melting for producing AlSi12 Parts using ANOVA.
    (MDPI, 2024-07-23) Kekana, Neo; Shongwe, Mxolisi Brendon; Mpofu, Khumbulani; Muvunzi, Rumbidzai
    In this study, AlSi12 alloy samples were produced via the selective laser melting (SLM) technique to produce high-density components with complex and customized parts for railway applications. Nonetheless, the production of dense samples necessitates the optimization of production process parameters. As a statistical design of the experimental method, response surface methodology was applied to optimize different combinations of SLM parameters. The outcomes were analyzed via analysis of variance (ANOVA) and signal-to-noise(S/N) ratios. The relationship between the hardness response to the process parameters (scanning speed and laser power) for determining the optimal processing conditions were examined. A hardness value of 133 HV was obtained. The process parameters were successfully optimized and the relationship between the parameters and the structures of the fabricated samples were reported.