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Item Advancing Energy Storage Technology through Hybridization of Supercapacitors and Batteries: A Review on the Contribution of Carbon-Based Nanomaterials.(Purpose-LED Publishing, 2021-01-01)Fast depletion of fossil fuel and other non-renewable energy resources with their negative environmental impact have raised the quest for eco-friendly and sustainable energy resources. Sustainable energy resources such as solar and wind energy are periodical. Therefore, such energy resources can only be effectively utilized with advanced energy storage technology. Currently, various energy storage technologies such as batteries and supercapacitors are available with various energy storage properties. For instance, batteries are characterized with high energy and low power density. On the other hand, supercapacitors are low energy and high power density devices. The high power density of supercapacitors results to their faster charging and discharging capability compared to batteries. While batteries can accommodate higher energy compared to supercapacitors. Therefore, to obtain single energy storage material/device with both high energy and power density is a challenge in the energy storage sector. However, various efforts have been made to address this challenge through combinations of various materials or devices. For instance, carbon-based nanomaterials such as graphene and carbon nanotubes have been extensively studied in design of supercapacitors for high energy storage density. While supercapacitors and batteries have been hybridized on the effort to obtain energy storage device with both high energy and power density for advanced energy storage technology. Therefore, this review looks into the contribution of carbon-based nanomaterials in improving energy storage density of supercapacitors and their hybridization with batteries as the way forward to obtain energy storage materials/devices with both high energy and power density for advanced energy storage technology.Item Silica nanofillers-reinforced polyimide composites for mechanical, thermal, and electrical insulation applications and recommendations: a review.(Purpose-LED Publishing, 2022-01-01)Owing to the specific properties of polyimide, its nanocomposites have in recent years shown to be a promising polymer composite for mechanical, thermal, and electrical insulation applications. Studies have in many ways revealed the utilization of the polyimide reinforced nanofillers in the area of insulation practice be it thermal or electrical insulation. However, reinforced polyimide nanocomposites were observed to undergo interfacial bonding issues that have badly influenced their insulation behaviour during service. Dielectric properties and electrical discharge (corona discharge) resistance lifespan of polyimide composites are found degrading during long periods of exposure to elevated temperature conditions. Notwithstanding, efforts have been made on improving the electrical and thermal insulation behaviour of polyimide nanocomposites. As such, the current review study focused on the influence of silica nanoparticles on the thermal, electrical, and mechanical characteristics of polyimide matrix composites for insulation practice and applications. Thus, the vision of the authors is to contribute to the future trend of designing and processing polyimide nanocomposites for insulation applications. Thus, the authors ended the article with furtherance, challenges, and recommendations of further enhancement of polyimide nanocomposites as a candidate material for insulation (electrical and thermal). Hence, the study will pave the way for future studies.Item ABPBI/MWCNT for proton radiation shielding in low earth orbit.(American Institute of Physics (AIP), 2023-06-14)When planning for any space mission, shielding against ionizing radiation is essential. Polymers, combined with a nano-filler material to reinforce and enhance the polymer properties, can provide a sufficient radiation shielding function with lower weight and less secondary radiation generation than traditional shielding materials such as aluminum and high-density polyethylene. In this study, poly (2, 5) benzimidazole/multiwalled carbon nanotube (ABPBI/MWCNT) nanocomposites were fabricated and evaluated for their proton radiation shielding capabilities in the low-earth orbit region of space. The radiation shielding effectiveness of the ABPBI/MWCNT nanocomposites was experimentally evaluated by comparing their proton transmission properties and their secondary neutron generation to those of pristine ABPBI. The results showed that adding MWCNTs to the ABPBI matrix further reduced the secondary neutrons generated by the pristine ABPBI. In addition, the depth profile showed that proton penetration into the bulk of the composite decreased as the MWCNT weight percentage loading increased. The MWCNT-loaded composites showed improved resistance to proton radiation-induced damage compared to the pristine ABPBI membrane. This was evident from the visible damage observed in the scanning electron microscopy micrographs of the pre- and post-irradiated ABPBI membranes. Furthermore, composites containing MWCNTs displayed improved thermal stability over the pristine ABPBI for both pre- and post-irradiation composites. The overall characteristics presented have shown ABPBI/MWCNT nanocomposites as an effective material for application in the space industry.Item Speciation of Cr(VI) in environmental samples in the vicinity of the ferrochrome smelter.(Elsevier B.V., 2009-07-23)The impact of ferrochrome smelter on the contamination of its environment with toxic hexavalent chromium, Cr (VI), was assessed by analyzing smelter dusts, soil, grass and tree barks. For the separation of Cr (VI) from Cr (III), solid samples were treated with 0.1MNa2CO3 and filtered through hydrophilic PDVF 0.45mfilter prior to the determination of Cr (VI) by electrothermal atomic absorption spectrometry (ET–AAS). Ferrochrome smelter dust was found to contain significant levels of Cr (VI), viz. 43.5gg−1 (cyclone dust), 2710gg−1 (fine dust), and 7800gg−1 (slimes dust) which exceeded the maximum acceptable risk concentration (20gg−1). The concentration of Cr (VI) in environmental samples of grass (3.4±0.2), soil (7.7±0.2), and tree bark (11.8±1.2) collected in the vicinity of the chrome smelter were higher as compared with the same kind of samples collected from uncontaminated area. The results of the investigation show that ferrochrome smelter is a source of environmental pollution with contamination factors of Cr (VI) ranging between 10 and 50.Item Small-scale recovery of noble metals from jewellery wastes.(Elsevier, 2004-11-01)This paper describes an investigation to separate and selectively recover silver, gold and platinum from jewellery and laboratory wastes, and produce technical grade material suitable for training purposes. Nitric acid was employed to dissolve and separate silver and other impurities from gold and platinum, which were then dissolved in aqua regia and precipitated selectively. The current work quantified the effects of temperature, stirring rate, leaching agent concentration and solid: liquid ratio on the recovery of the various noble metals and in summary yielded the optimum treatment conditions in each case. It was found that increased leaching reagent concentration (in the case of Ag), temperatures and stirring rates enhanced the recovery kinetics and optimum yield of the three noble metals. An increased liquid to solid ratio also enhanced the recovery of the silver. Recovery yields 97.1%, 99.9% and 99.4% for silver, gold and platinum, respectively, were obtained. The recovered silver, gold and platinum had purities of, respectively, 98.3%, 99.1% and 99.0%. A cost saving of approximately R10 000 per kilogram of scrap refined could be achieved by the in-house treatment of the waste, not to mention the time-saving benefit.
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