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Item ABPBI/MWCNT for proton radiation shielding in low earth orbit.(American Institute of Physics (AIP), 2023-06-14)When planning for any space mission, shielding against ionizing radiation is essential. Polymers, combined with a nano-filler material to reinforce and enhance the polymer properties, can provide a sufficient radiation shielding function with lower weight and less secondary radiation generation than traditional shielding materials such as aluminum and high-density polyethylene. In this study, poly (2, 5) benzimidazole/multiwalled carbon nanotube (ABPBI/MWCNT) nanocomposites were fabricated and evaluated for their proton radiation shielding capabilities in the low-earth orbit region of space. The radiation shielding effectiveness of the ABPBI/MWCNT nanocomposites was experimentally evaluated by comparing their proton transmission properties and their secondary neutron generation to those of pristine ABPBI. The results showed that adding MWCNTs to the ABPBI matrix further reduced the secondary neutrons generated by the pristine ABPBI. In addition, the depth profile showed that proton penetration into the bulk of the composite decreased as the MWCNT weight percentage loading increased. The MWCNT-loaded composites showed improved resistance to proton radiation-induced damage compared to the pristine ABPBI membrane. This was evident from the visible damage observed in the scanning electron microscopy micrographs of the pre- and post-irradiated ABPBI membranes. Furthermore, composites containing MWCNTs displayed improved thermal stability over the pristine ABPBI for both pre- and post-irradiation composites. The overall characteristics presented have shown ABPBI/MWCNT nanocomposites as an effective material for application in the space industry.Item Speciation of Cr(VI) in environmental samples in the vicinity of the ferrochrome smelter.(Elsevier B.V., 2009-07-23)The impact of ferrochrome smelter on the contamination of its environment with toxic hexavalent chromium, Cr (VI), was assessed by analyzing smelter dusts, soil, grass and tree barks. For the separation of Cr (VI) from Cr (III), solid samples were treated with 0.1MNa2CO3 and filtered through hydrophilic PDVF 0.45mfilter prior to the determination of Cr (VI) by electrothermal atomic absorption spectrometry (ET–AAS). Ferrochrome smelter dust was found to contain significant levels of Cr (VI), viz. 43.5gg−1 (cyclone dust), 2710gg−1 (fine dust), and 7800gg−1 (slimes dust) which exceeded the maximum acceptable risk concentration (20gg−1). The concentration of Cr (VI) in environmental samples of grass (3.4±0.2), soil (7.7±0.2), and tree bark (11.8±1.2) collected in the vicinity of the chrome smelter were higher as compared with the same kind of samples collected from uncontaminated area. The results of the investigation show that ferrochrome smelter is a source of environmental pollution with contamination factors of Cr (VI) ranging between 10 and 50.Item Small-scale recovery of noble metals from jewellery wastes.(Elsevier, 2004-11-01)This paper describes an investigation to separate and selectively recover silver, gold and platinum from jewellery and laboratory wastes, and produce technical grade material suitable for training purposes. Nitric acid was employed to dissolve and separate silver and other impurities from gold and platinum, which were then dissolved in aqua regia and precipitated selectively. The current work quantified the effects of temperature, stirring rate, leaching agent concentration and solid: liquid ratio on the recovery of the various noble metals and in summary yielded the optimum treatment conditions in each case. It was found that increased leaching reagent concentration (in the case of Ag), temperatures and stirring rates enhanced the recovery kinetics and optimum yield of the three noble metals. An increased liquid to solid ratio also enhanced the recovery of the silver. Recovery yields 97.1%, 99.9% and 99.4% for silver, gold and platinum, respectively, were obtained. The recovered silver, gold and platinum had purities of, respectively, 98.3%, 99.1% and 99.0%. A cost saving of approximately R10 000 per kilogram of scrap refined could be achieved by the in-house treatment of the waste, not to mention the time-saving benefit.Item Antimicrobial activity of limonene enantiomers and 1,8-cineole alone and in combination.(Wiley, 2007-08-23)Two common essential oil constituents, 1,8-cineole and limonene, were assessed for antimicrobial activity, using the minimum inhibitory concentration (MIC) microtitre plate method against eight organisms. The limonene enantiomers, i.e. (+), (−) and the racemate, singularly and in combination (1:1) with 1,8-cineole, were investigated to establish possible interactions. The MIC values were in the ranges 3–27 mg/ml for (+)-limonene; 2–27 mg/ml for (−)-limonene and 23 mg/ml for 1,8-cineole, depending on the pathogen studied. The combinations, when investigated in a 1:1 ratio, mostly indicated reduced activity. Using various ratios of limonene and 1,8-cineole, the specific interaction was further investigated against Staphylococcus aureus (Gram-positive), Pseudomonas aeruginosa (Gram-negative) and a yeast, Cryptococcus neoformans. A figurative representation of the results using isobologram construction indicated that, depending on the ratio and specific enantiomer, an additive, synergistic or antagonistic interaction may be observed.Item The antimicrobial activity of four commercial essential oils in combination with conventional antimicrobials.(Oxford University Press (OUP), 2008-11-17)Aims: Due to the emergence of multi-drug resistance, alternatives to conventional antimicrobial therapy are needed. This study aims to investigate the in vitro pharmacological interactions between essential oils (considered valuable as natural therapeutic treatments) and conventional antimicrobials (ciprofloxacin ⁄ amphotericin B) when used in combination. Methods and Results: Interactions of the essential oils (Melaleuca alternifolia, Thymus vulgaris, Mentha piperita and Rosmarinus officinalis) when combined with ciprofloxacin against Staphylococcus aureus indicate mainly antagonistic profiles. When tested against Klebsiella pneumoniae the isobolograms show antagonistic, synergistic and additive interactions depending on the combined ratio. The R. officinalis ⁄ ciprofloxacin combination against K. pneumoniae displayed the most favourable synergistic pattern. The interactions of M. alternifolia (tea tree), T. vulgaris (thyme), M. piperita (peppermint) and R. officinalis (rosemary) essential oils with amphotericin B indicate mainly antagonistic profiles when tested against Candida albicans. Conclusion: While a number of interactions show complete antagonism, others show varied (synergistic, additive and ⁄ or antagonistic) interactions, thus the efficacy is dependent on the ratio in which the two components co-exist. Significance and Impact of the Study: The predominant antagonistic interactions noted here, suggests that some natural therapies containing essential oils should be used with caution when combined with antibiotics.
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