TUT DIGITAL OPEN REPOSITORY

Recent Submissions

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    Speciation of Cr(VI) in environmental samples in the vicinity of the ferrochrome smelter.
    (Elsevier B.V., 2009-07-23) Sedumedi, Hilda N.; Mandiwana, Khakhathi L.; Ngobeni, Prince; Panichev, Nikolay
    The impact of ferrochrome smelter on the contamination of its environment with toxic hexavalent chromium, Cr (VI), was assessed by analyzing smelter dusts, soil, grass and tree barks. For the separation of Cr (VI) from Cr (III), solid samples were treated with 0.1MNa2CO3 and filtered through hydrophilic PDVF 0.45mfilter prior to the determination of Cr (VI) by electrothermal atomic absorption spectrometry (ET–AAS). Ferrochrome smelter dust was found to contain significant levels of Cr (VI), viz. 43.5gg−1 (cyclone dust), 2710gg−1 (fine dust), and 7800gg−1 (slimes dust) which exceeded the maximum acceptable risk concentration (20gg−1). The concentration of Cr (VI) in environmental samples of grass (3.4±0.2), soil (7.7±0.2), and tree bark (11.8±1.2) collected in the vicinity of the chrome smelter were higher as compared with the same kind of samples collected from uncontaminated area. The results of the investigation show that ferrochrome smelter is a source of environmental pollution with contamination factors of Cr (VI) ranging between 10 and 50.
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    Small-scale recovery of noble metals from jewellery wastes.
    (Elsevier, 2004-11-01) Potgieter, J.H.; Potgieter, S.S.; Mbaya, R.K.K.; Teodorovic, A.
    This paper describes an investigation to separate and selectively recover silver, gold and platinum from jewellery and laboratory wastes, and produce technical grade material suitable for training purposes. Nitric acid was employed to dissolve and separate silver and other impurities from gold and platinum, which were then dissolved in aqua regia and precipitated selectively. The current work quantified the effects of temperature, stirring rate, leaching agent concentration and solid: liquid ratio on the recovery of the various noble metals and in summary yielded the optimum treatment conditions in each case. It was found that increased leaching reagent concentration (in the case of Ag), temperatures and stirring rates enhanced the recovery kinetics and optimum yield of the three noble metals. An increased liquid to solid ratio also enhanced the recovery of the silver. Recovery yields 97.1%, 99.9% and 99.4% for silver, gold and platinum, respectively, were obtained. The recovered silver, gold and platinum had purities of, respectively, 98.3%, 99.1% and 99.0%. A cost saving of approximately R10 000 per kilogram of scrap refined could be achieved by the in-house treatment of the waste, not to mention the time-saving benefit.
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    Antimicrobial activity of limonene enantiomers and 1,8-cineole alone and in combination.
    (Wiley, 2007-08-23) Van Vuuren, S.F.; Viljoen, A.M.
    Two common essential oil constituents, 1,8-cineole and limonene, were assessed for antimicrobial activity, using the minimum inhibitory concentration (MIC) microtitre plate method against eight organisms. The limonene enantiomers, i.e. (+), (−) and the racemate, singularly and in combination (1:1) with 1,8-cineole, were investigated to establish possible interactions. The MIC values were in the ranges 3–27 mg/ml for (+)-limonene; 2–27 mg/ml for (−)-limonene and 23 mg/ml for 1,8-cineole, depending on the pathogen studied. The combinations, when investigated in a 1:1 ratio, mostly indicated reduced activity. Using various ratios of limonene and 1,8-cineole, the specific interaction was further investigated against Staphylococcus aureus (Gram-positive), Pseudomonas aeruginosa (Gram-negative) and a yeast, Cryptococcus neoformans. A figurative representation of the results using isobologram construction indicated that, depending on the ratio and specific enantiomer, an additive, synergistic or antagonistic interaction may be observed.
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    The antimicrobial activity of four commercial essential oils in combination with conventional antimicrobials.
    (Oxford University Press (OUP), 2008-11-17) Van Vuuren, S.F.; Suliman, S.; Viljoen, A.M.
    Aims: Due to the emergence of multi-drug resistance, alternatives to conventional antimicrobial therapy are needed. This study aims to investigate the in vitro pharmacological interactions between essential oils (considered valuable as natural therapeutic treatments) and conventional antimicrobials (ciprofloxacin ⁄ amphotericin B) when used in combination. Methods and Results: Interactions of the essential oils (Melaleuca alternifolia, Thymus vulgaris, Mentha piperita and Rosmarinus officinalis) when combined with ciprofloxacin against Staphylococcus aureus indicate mainly antagonistic profiles. When tested against Klebsiella pneumoniae the isobolograms show antagonistic, synergistic and additive interactions depending on the combined ratio. The R. officinalis ⁄ ciprofloxacin combination against K. pneumoniae displayed the most favourable synergistic pattern. The interactions of M. alternifolia (tea tree), T. vulgaris (thyme), M. piperita (peppermint) and R. officinalis (rosemary) essential oils with amphotericin B indicate mainly antagonistic profiles when tested against Candida albicans. Conclusion: While a number of interactions show complete antagonism, others show varied (synergistic, additive and ⁄ or antagonistic) interactions, thus the efficacy is dependent on the ratio in which the two components co-exist. Significance and Impact of the Study: The predominant antagonistic interactions noted here, suggests that some natural therapies containing essential oils should be used with caution when combined with antibiotics.
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    Lions in the Kgalagadi Transfrontier Park: Modelling the effect of human-caused mortality.
    (Blackwell Publishing Ltd., 2004-01-15) Van Vuuren, Jan H.; Herrmann, Eric; Funston, Paul J.
    An age-structured demographic matrix model is developed to determine the long-term viability of the Southern African Kgalagadi Transfrontier Park lion (Panthera leo) population that is subjected to persecution along the park boundaries. In doing so, maximum sustainable persecution rates are established, so that efficient conservation measures may be taken, if required, to ensure the continued survival of the species in the park. Sensitivity analyses indicate that adult female survival ability alone is the most important component of the model in terms of long-term population survival. Furthermore, these analyses show that the boundary prides of the park are able to increase their chances of survival and are able to sustain significantly higher human-caused mortality rates by inducing birth-sex ratio biases in favour of females. The model suggests that the persecution rate experienced by the study population over the period 1998–2001 cannot be sustained in the long term, provided that there is no immigration of adult females into the population from the park interior. To ensure the survival of existing park boundary prides, adult lionesses should, as far as possible, be afforded protection from persecution, so that park boundary populations do not merely serve as population sinks for lions from elsewhere or become extinct.